Intermolecular charge transfer (CT) states at the interface between electron-donating and electron-accepting (A) materials in organic thin films are characterized by absorption and emission bands within the optical gap of the interfacing materials. Depending on the used donor and acceptor materials, CT states can be very emissive, or generate free carriers at high yield. The former can result in rather efficient organic light emitting diodes, via thermally activated delayed fluorescence, while the latter property is exploited in organic photovoltaic devices and photodetectors. In this contribution, we will discuss the fundamental properties of CT states and link them to organic opto-electronic device performance. We will discuss the influence of intra- and inter-molecular properties, such as the energy of the CT state, the electronic coupling between electron donor and acceptor, the molecular reorganization energy as well as non-radiative triplet states on radiative and non-radiative free carrier recombination. Furthermore, we introduce a new device concept, using an optical cavity resonance effect to boost CT absorption at photon energies below the optical gap of both donor and acceptor, enabling narrow-band, near infrared (NIR) photo-detection. Our findings imply that the power conversion efficiency of organic photovoltaics and maximum achievable detectivities for organic NIR detectors are limited by the presence of high energy vibrational modes and electron-phonon coupling, intrinsic to organic semiconductors.
Micro-mechanical oscillators are attractive systems to begin probing quantum mechanics at the mesoscopic level. Recent advances in technology are beginning to allow quantum control over the motional degrees of freedom of such micro-mechanical oscillators. Here, I will introduce the 'displacemon' - an electromechanical architecture that couples a vibrating nanobeam, e.g. a carbon nanotube, to a superconducting qubit. This platform can achieve strong and even ultrastrong coupling enabling a variety of quantum protocols, in particular, I'll describe a protocol for generating and measuring quantum interference between two trajectories of the mechanical oscillator. I'll demonstrate the feasibility of generating a spatially distinct quantum superposition state of motion containing more than 10^6 nucleons, and discuss the signatures of a fully quantum (as opposed to classical) oscillator.
Studying reactions between two unstable species has been an ongoing experimental challenge. I will present our new approach to this old problem: combining a source of cold radicals with Coulomb-crystallised ions held within an ion trap.
Studying ion-radical collisions in this way offers a number of advantages, including the ability to detect reactions with high sensitivity and excellent control over the reaction conditions. Preliminary studies involving charge exchange between Coulomb-crystallised ions held within a linear Paul ion trap and cold neutral molecules will be presented. For quantitative analysis, a mass-sensitive detection method is adopted - with the ejection of all ions onto an external detector at a selected time. This time-of-flight mass spectrometry (ToF-MS) approach removes ambiguity about the identities of dark ions: both the masses and relative numbers of all trapped species at the point of ejection can be ascertained directly from the ToF trace.
Combining ToF-MS detection capabilities with real-time imaging of the Coulomb crystal enables one to examine both the kinetics and the dynamics of ion-neutral reactions. Our source of cold radical species, a Zeeman decelerator, will be described and the clever (in my opinion) way that we gain optimal performance will be explained. Finally, I will present our designs for a combined Zeeman decelerator-ion trap apparatus, and discuss our progress to date.
Many of the properties of atoms or molecules in highly excited Rydberg states have a strong dependence on the principal quantum number, n. Laser excitation to these states can be used to attain long lifetimes, macroscopic classical radii, or extremely large electric dipole moments. Applications that exploit the novel attributes of Rydberg systems are being developed in the fields of quantum information processing, exotic chemistry, and antimatter research. In this talk, I'll provide an overview Rydberg atoms and I will also discuss the process of Rydberg-Stark deceleration with inhomogeneous electric fields. This technique can be employed to exert control over any Rydberg system, including the part-antimatter positronium atom.
Vortex beams refer to freely-propagating particle beams constituted of electrons or photons, carrying quantized orbital angular momentum (OAM) about their axis of propagation. Allen was the first to forward the theory of optical vortices with intrinsic OAM. The recently proposed concept of electron vortex beams is interesting because electrons carry spin and charge, making EVBs potential candidates for applications ranging from atomic physics to quantum information and spintronics. In this talk I will mainly focus on the spintronics applications of Electron vortex beams.
Determining whether the correlations between two systems are quantum or classical is fundamental to our understanding of the physical world and our ability to use such correlations for technological applications. The common approach is to ask about the properties of measurement statistics using different types of resources, resulted in the standard classification of quantum correlations in quantum information, namely entanglement  and discord [2,3].
Here, we pose the quantum-classical separation problem from a computational perspective and try to provide a consistent solution to it. We ask "what do we infer about quantumness of correlations from the supremacy of collaborative quantum computations?" We investigate the answer to this question within both continuous variable domain (i.e., bosonic systems)  and discrete variable domain  and find that a separation between classical and quantum correlations is possible from computational viewpoint.
Within both regimes, we show that the global coherence of the input quantum states to the computational models provide the necessary and necessary-and-sufficient resources for the collaborative quantum advantage, respectively. We show that our generalized definition of quantum correlations properly and consistently contains the standard classifications of quantum optics and quantum information. As such, Bell nonlocality, entanglement, discord, and global phase-space nonclassicality  are only manifestations of net global coherence. Last but not least, we provide an operational interpretation of such correlations as those allowing two distant parties to increase their respective local quantum computational resources only using locally classical operations and classical communication.
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 L. Henderson and V. Vedral, Classical, Quantum, and Total Correlations, J. Phys. A 34, 6899 (2001).
 H. Ollivier and W. H. Zurek, Quantum Discord: A Measure of the Quantumness of Correlations, Phys. Rev. Lett. 88, 017901 (2001).
 F. Shahandeh, A. P. Lund, and T. C. Ralph, Quantum Correlations in Nonlocal Boson Sampling, Phys. Rev. Lett. 119, 120502 (2017).
 F. Shahandeh, A. P. Lund, and T. C. Ralph, Quantum Correlations and Global Coherence in Distributed Quantum Computing, arXiv:1706.00478 [quant-ph].
 W. Vogel and D.-G. Welsch, Quantum Optics, (Wiley-VCH, Weinheim, 2006).
Recent experimental progress [1,2] indicates that selective and strong optical driving of phonons may generate or enhance ordered phases in strongly correlated quantum materials. This is achieved by driving the system far out of thermal equilibrium on a very short time scale where the dynamics is dominated by coherent quantum evolution. In my talk I will discuss a collection of approaches for gaining a better understanding of the fundamental physical processes that might underpin these experiments. I will focus on the study of driven toy models and also mention novel approaches to the simulation of strongly correlated quantum systems as well as quantum optics based experiments. The long term aim of this work is to help developing optimized methods for optically controlling and steering dynamics far away from thermal equilibrium in quantum matter to induce new functionality.
Specifically, I will consider a one-dimensional driven fermionic Hubbard model in the strongly correlated limit where the onsite interaction dominates over the kinetic energy . The driving is modelled as an alternating periodic modulation of the lattice site energy offsets. I will show how this modulation suppresses tunnelling and induces exchange interactions. The combination of these effects changes the nature of the system into an attractive Luttinger liquid and leads to enhanced fermion pairing in one spatial dimension. I will present results at zero and finite temperatures and discuss the prospect of observing driven out-of-equilibrium superconductivity in this model system. I will then move to novel hybrid quantum-classical approaches for DMFT simulations that promise to yield insights into the driven Hubbard model in higher spatial dimensions.
 D. Fausti, R. I. Tobey, N. Dean, S. Kaiser, A. Dienst, M. C. Hoffmann, S. Pyon, T. Takayama, H. Takagi, and A. Cavalleri, Light-Induced Superconductivity in a Stripe-Ordered Cuprate, Science 331, 189 (2011).
 M. Mitrano, A. Cantaluppi, D. Nicoletti, S. Kaiser, A. Perucchi, S. Lupi, P. Di Pietro, D. Pontiroli, M. Ricco, S.R. Clark, D. Jaksch and A. Cavalleri, Possible light-induced superconductivity in K3C60 at high temperature, Nature 530, 461-464 (2016).
 J. Coulthard, S.R. Clark, S. Al-Assam, A. Cavalleri and D. Jaksch, Enhancement of super-exchange pairing in the periodically-driven Hubbard model, Phys. Rev. B 96, 085104 (2017).
Simulating quantum physics is still today a very challenging problem due to the very large size of the Hilbert spaces that typically grows exponentially with the degrees of freedom. This property imposes significant limitations in calculating the ground states of quantum many-body Hamiltonians and determing the time evolution. In recent years, a new simulation method, called quantum simulation, have become increasingly popular in order to circumvent these difficulties. The basic idea is very simple: to use some fully controllable quantum system, called quantum simulator, to emulate and to analyze the original problem. We will explore these ideas from a theoretical point of view, focusing on the simulation of Schwinger model for (1+1)D Quantum Electrodynamics. In doing so, we use a new Zn--approach and numerical techniques, such as DMRG, in order to determine the effectiveness of the model in reproducing the main features and phenomenology of the target theory.
Quantum dot architectures have undeniably regained interest for quantum information despite enormous progress in the realisation and the control of both electron and nuclear spin donor-based qubits. Most of the current research concentrates on Metal-Oxide-Semiconductor (MOS) based structures. However, the use of high doped silicon and constrictions provides an alternative way to define metallic-like quantum dots while reducing significantly the number of connections. Our qubit and detector design reflects these ideas. Scalability is further improved by lithographically defining isolated double quantum dots that are used to carry charge qubit states. I will show how, in such particular configuration, qubit states can be read and manipulated with great accuracy by either DC gate or microwave pulses. In particular, I will present both theoretical and experimental investigations, discussing the major differences between doped and MOS-type devices on the operation, the scalability as well as the extremely and surprisingly long coherence times observed.
Part of this work has been supported by the Project for Developing Innovation Systems of the Ministry of Education, Culture, Sports, Science and Technology (MEXT), Japan
I review the notions of bare (unprotected) quantum devices (QD), externally protected QDs  and internally protected QDs. Quantum topological states are used as a resource to achieve for the first time a fully-fledged quantum device like a quantum computer, including self-correcting initialization, measurements and quantum gates . This construction is based on Topological Color Codes [3,4] which have very nice and powerful transversality properties which allow them to perform quantum tasks like topological quantum distillation, teleportation, dense coding etc. There are recent experimental small realizations of Topological Color Codes using a trapped-ion platform . The underlying physical phenomena in these new quantum devices is the notion of topological order: a new paradigm in strongly correlated systems. We show how quantum topologically protected states can be constructed not only in 2D space but also in higher dimensional systems .
1 "Error Threshold for Color Codes and Random 3-Body Ising Models" H. G. Katzgraber, H. Bombin, M. A. Martin-Delgado; Phys. Rev. Lett. 103, 090501 (2009) 2 "Self-Correcting Quantum Computers" H. Bombin, R. W. Chhajlany, M. Horodecki, M.A. Martin-Delgado; New Journal of Physics 15 (5), 055023 (2013). 3 "Topological Quantum Distillation" H. Bombin, M.A. Martin-Delgado; Phys.Rev.Lett. 97 (2006) 180501 4 "Topological Computation without Braiding" H. Bombin, M.A. Martin-Delgado; Phys.Rev.Lett.98:160502, (2007) 5 "Quantum computations on a topologically encoded qubit" D. Nigg, M. Muller, E. A. Martinez, P. Schindler, M. Hennrich, T. Monz, M. A. Martin-Delgado, R. Blatt; Science Vol. 345 no. 6194 pp. 302-305 (2014). 6 "Exact Topological Quantum Order in D=3 and Beyond: Branyons and Brane-Net Condensates" H. Bombin, M.A. Martin-Delgado; Phys.Rev.B75:075103, (2007)
Fluorescence microscopy is popular in the life sciences due to its molecular specificity and non-invasiveness. Here, I will outline three methods we are using to study how biophysical mechanisms regulate the activation of T cells, a key regulator of the adaptive immune system.
Firstly, single-molecule super-resolution microscopy combined with novel statistical analysis which we use to describe the nanoscale clustering of cell surface molecules and the nanoscale ultrastructure of the cell skeleton. Second, structured illumination super-resolution microscopy combined with image correlation approaches to quantify molecular flows in cells including those of the cell skeleton and the cell membrane. Finally, environmentally sensitive membrane dyes which report on their local biophysical and biochemical environments to study molecular organisation in the cell membrane. Together, these methods show how macroscale events - such as an immune response - can be regulated by nanoscale spatio-temporal molecular organisation.
I will describe the applicability to problems of slow relaxation and non-equilibrium in the dynamics of quantum many-body systems of concepts more frequently associated with classical soft matter systems such as glasses. I will discuss how quantum slow dynamics arises from local dynamical constraints, how collective relaxation is a phenomenon dominated by spatial fluctuations in the dynamics, and whether quantum non-ergodicity - termed many-body localisation - can arise in systems without disorder. I will also discuss experimentally relevant issues such as the effect of dissipation and how to probe the growth of entanglement and coherence in these systems.
We will discuss our trapping and cooling experiments of optically levitated nanoparticles . We will report on the cooling of all translational motional degrees of freedom of a single trapped silica particle to ~1mK simultaneously at vacuum of 10-5 mbar using a parabolic mirror to form the optical trap. We will further report on the squeezing of a thermal motional state of the trapped particle by rapid switch of the trap frequency .
We will further discuss ideas to experimentally test quantum mechanics by means of collapse models  by both matter-wave interferometry  and non-interferometric methods . While first experimental bounds by non-interferometric tests have been achieved during the last year by a number of different experiments , we at Southampton work on setting up the Nanoparticle Talbot Interferometer (NaTalI) to test the quantum superposition principle directly for one million atomic mass unit particles.
We will further discuss some ideas to probe the interplay between quantum mechanics and gravitation by (levitated) optomechanics experiments. One idea is to seek experimental evidence about the fundamentally quantum vs classical nature of gravity by using the torsional motion of a non-spherical trapped particle, while another idea is to test the existence of a gravity related shift of energy levels of the mechanical harmonic oscillator, which is predicted by semi-classical gravity (the so-called Schrdinger-Newton equation) .
One of the main challenges to the construction of a scalable quantum computer is the extreme sensitivity of quantum information to environmental noise and instrumental imperfections. On the theoretical front, several strategies have been proposed to mitigate errors and perform successful computations in the presence of noise. Most of these quantum error correction (QEC) strategies have been designed for incoherent noise, which typically arises from stochastic interactions with the environment. Recently, it has been pointed out by several authors that coherent errors, which arise from instrumental miscalibrations, can corrupt quantum information to a much higher degree than incoherent errors. It is not clear whether or not traditional QEC methods can be protective against this type of noise. To tackle this problem, we have devised a simulation technique to accurately measure how effective QEC is to mitigate coherent errors. We have found that QEC transforms noise from coherent to effectively semi-coherent . Furthermore, ongoing work in our group suggests that subsequent levels of QEC can transform coherent noise to completely incoherent. This means that, although coherent noise can be extremely deleterious to quantum information, a clever application of QEC can reduce the noise to tolerable levels, which relaxes the stringent experimental demands needed to build a quantum computer.
 M. Gutierrez et al., Phys. Rev. A 94, 042338 (2016)
The distinction between fundamental noise (such as that induced by effective collapse or quantum gravity models) and environmental one (due to the coupling to a well identified environment) is a challenging objective, since the two forms of noise have identical dynamical consequences.
Inspired by the notion that environmental noise is in principle observable, whilst fundamental noise would not be, we study the estimation of the diffusion parameter induced by wave function collapse models under continuous monitoring of the environment. We will thus show that monitoring can break the symmetry between the roles of fundamental and environmental noise parameters, and thus improve the upper bounds one can put on the former.
In this pedagogical talk, we will derive our result in detail from first principles, taking into account finite measurement efficiencies and, in order to quantify the advantage granted by monitoring, also analysing the quantum Fisher information associated with a diffusion parameter.
The study of light propagation through thermal atomic vapours subject to external magnetic fields is a flourishing area of research. At Durham we have spent 15 years studying the spectroscopy of alkali-metal vapours, culminating in the publication of our electric susceptibility code ElecSus (Zentile et al. Computer Physics Communications 189 162-174 (2015)). The applications range from devices (a compact optical isolator, narrow-line filters) to fundamental physics (measuring the cooperative Lamb shift, a possible new method to measure Boltzmann's constant).
In the talk I will describe experimental and theoretical work to model the electric susceptibility of a vapour of alkali-metal atoms; and finish with an outlook for cooperative quantum optics in thermal vapours.
While ultracold atoms have been very successful in probing closed equilibrium condensed matter phenomena, open non-equilibrium quantum systems have attracted a strong and growing interest recently because of their rich dynamics and nontrivial steady states. Exciton-polaritons (polaritons) have emerged as a prime candidate for the non-equilibrium system of interacting bosons.
Polaritons are mixed light-matter bosons resulting from the strong coupling of photons in a microcavity and excitons in a quantum well which can condense into macroscopically coherent many-body states. As a prime example of the non-equilibrium nature of polariton condensates, we have shown recently that polariton condensates can spontaneously magnetize, and we can control their spin optically and electronically. Interestingly, the direction of the spin of two coupled condensates can be also controllably aligned (or anti-aligned). Hence, a lattice of polariton condensates is expected to model a non-equilibrium interacting spin system with unusual properties. I will address this and show you some very interesting and surprising recent results from our labs.
In this talk, I will review the main properties of topological insulators, i.e. holographic phases of matter with an insulating bulk but conducting boundaries, characterised by a topological invariant.
I will emphasise the connection between condensed matter and lattice Gauge theory concepts, and review possible implementations in the field of atomic atomic, molecular, and optical (AMO) physics.
This connection allows us to introduce lower-dimensional 'toy' models where strong-correlation effects brought by interactions can be understood both analytic and numerically, and where cold-atom experiments can be used to test our predictions.
Cold atom experiments come in many forms, usually in large scale vacuum chambers too bulky for practical devices beyond the laboratory, but many are being translated to more compact forms known as 'atom chips'. These are microfabricated wires patterned onto a substrate through which currents are passed to form various magnetic traps for atoms. Currently these chips, which are no larger than a postage stamp, are still housed in large vacuum chambers surrounded by a vast array of optics, laser, detectors and control electronics. If Quantum Technology is to truly make a significant impact we need to focus on miniaturizing and integrating this infrastructure as well. We aim to do this not with scaled-down copies of conventional components, but with mass-producable planar fabrication techniques, developed for semiconductor devices and MEMS, which we adapt to perform the roles of large scale apparatus.
Protecting resources in the form of quantum correlations, such as entanglement and quantum discord, against environmental noise, is of paramount importance towards the development of quantum technology. In this talk, we discuss how quantum correlations can be "frozen" over time, despite their exposure to environmental noise. We show that bipartite quantum correlations, such as quantum discord and other "discord-like" quantities, can be frozen by properly tuning the initial state subjected to the noise. We discuss a possible situation where bipartite entanglement, although being more fragile than the "discord-like" quantities, can be frozen by a suitable choice of quantum many-body system. We also demonstrate that the freezing of entanglement is a scale-invariant phenomenon in specific phases of some quantum spin models.
Bringing quantum science and technology to the space frontier offers exciting prospects for both fundamental physics and applications such as long-range secure communication and space-borne quantum probes for inertial sensing with enhanced accuracy and sensitivity. But despite promising proposals to exploit the significant advantages of space quantum missions, large-scale quantum test beds in space are yet to be realised due to the high costs and lead times of traditional 'Big Space' satellite development. But the 'small space' revolution, spearheaded by the rise of nanosatellites such as CubeSats, is an opportunity to greatly accelerate the progress of quantum space missions by providing easy and affordable access to space and encouraging agile development. We review space quantum science and technology, CubeSats and their rapidly developing capabilities and how they can be used to advance quantum satellite systems.
Preserving Quantum Information (coherence) is the main technical challenge on the road to Quantum Technology. The purpose of this talk is to introduce the noise models one commonly studies, and the countermeasures against decoherence which have been brought forward in the field of quantum control. We will try to define the jargon "non-Markovian" which is commonly discussed in this context and observe some intriguing mathematical contradictions. These will lead us to suggest a test for the validity of Schrödinger's Equation.